GSTDTAP  > 地球科学
DOI10.5194/acp-18-14965-2018
The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies
Constantin, Julian Gelman1,2,3; Gianetti, Melisa M.2; Longinotti, Maria P.2; Corti, Horacio R.1,2
2018-10-18
发表期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN1680-7316
EISSN1680-7324
出版年2018
卷号18期号:20页码:14965-14978
文章类型Article
语种英语
国家Argentina
英文摘要

In this work, we present new results of atomic force microscopy (AFM) force curves over pure ice at different temperatures, performed with two different environmental chambers and different kinds of AFM tips. Our results provide insight to resolve the controversy on the interpretation of experimental AFM curves on the ice-air interface for determining the thickness of the quasi-liquid layer (QLL). The use of a Mini Environmental Chamber (mEC) that provides an accurate control of the temperature and humidity of the gases in contact with the sample allowed us for the first time to get force curves over the ice-air interface without jump-in (jump of the tip onto the ice surface, widely observed in previous studies). These results suggest a QLL thickness below 1 nm within the explored temperature range ( - 7 to -2 degrees C). This upper bound is significantly lower than most of the previous AFM results, which suggests that previous authors overestimate the equilibrium QLL thickness, due to temperature gradients, or indentation of ice during the jump-in. Additionally, we proved that the hydrophobicity of AFM tips affects significantly the results of the experiments. Overall, this work shows that, if one chooses the experimental conditions properly, the QLL thicknesses obtained by AFM lie over the lower bound of the highly disperse results reported in the literature. This allows estimating upper boundaries for the QLL thicknesses, which is relevant to validate QLL theories and to improve multiphase atmospheric chemistry models.


领域地球科学
收录类别SCI-E
WOS记录号WOS:000447744000002
WOS关键词ATOMIC-FORCE MICROSCOPY ; X-RAY-SCATTERING ; MOLECULAR-DYNAMICS ; TRANSITION LAYER ; SURFACE ; FILMS ; GROWTH ; SNOW ; PHOTOCHEMISTRY ; SPECTROSCOPY
WOS类目Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
引用统计
文献类型期刊论文
条目标识符http://119.78.100.173/C666/handle/2XK7JSWQ/17246
专题地球科学
作者单位1.Comis Nacl Energia Atom, Dept Fis Mat Condensada, Ctr Atom Constituyentes, B1650KNA, Buenos Aires, DF, Argentina;
2.Univ Buenos Aires, Inst Quim Fis Mat Medio Ambiente & Energia UBA CO, Fac Ciencias Exactas & Nat, Pabellon 2,Ciudad Univ,C1428EGA, Buenos Aires, DF, Argentina;
3.Comis Nacl Energia Atom, Div Quim Atmosfer, Ctr Atom Constituyentes, B1650KNA, Buenos Aires, DF, Argentina
推荐引用方式
GB/T 7714
Constantin, Julian Gelman,Gianetti, Melisa M.,Longinotti, Maria P.,et al. The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2018,18(20):14965-14978.
APA Constantin, Julian Gelman,Gianetti, Melisa M.,Longinotti, Maria P.,&Corti, Horacio R..(2018).The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies.ATMOSPHERIC CHEMISTRY AND PHYSICS,18(20),14965-14978.
MLA Constantin, Julian Gelman,et al."The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies".ATMOSPHERIC CHEMISTRY AND PHYSICS 18.20(2018):14965-14978.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Constantin, Julian Gelman]的文章
[Gianetti, Melisa M.]的文章
[Longinotti, Maria P.]的文章
百度学术
百度学术中相似的文章
[Constantin, Julian Gelman]的文章
[Gianetti, Melisa M.]的文章
[Longinotti, Maria P.]的文章
必应学术
必应学术中相似的文章
[Constantin, Julian Gelman]的文章
[Gianetti, Melisa M.]的文章
[Longinotti, Maria P.]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。