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DOI | 10.1016/j.atmosres.2017.10.016 |
Ion balance and acidity of size-segregated particles during haze episodes in urban Beijing | |
Tian, Shili; Pan, Yuepeng; Wang, Yuesi | |
2018-03-01 | |
发表期刊 | ATMOSPHERIC RESEARCH |
ISSN | 0169-8095 |
EISSN | 1873-2895 |
出版年 | 2018 |
卷号 | 201页码:159-167 |
文章类型 | Article |
语种 | 英语 |
国家 | Peoples R China |
英文摘要 | In this study, we investigated how the ion balance causes variations in size segregated aerosol acidity and atmospheric processing on clean versus hazy days using a 9-stage sampler. We calculated the ratios (in charge equivalents, R-c/A) between measured cations (Na+, NH4+, K+, Mg-2 (+), and Ca-2(+)) and anions (SO42-, NO3- and C1-) for different aerosol size fractions. The ratios were typically close to unity in the accumulation mode (0.65-2.1 gm), and increased significantly when the particle size increased or decreased. In the coarse size range (aerodynamic diameter > 2.1 mu m), high R-c/A values were most likely caused by the undetermined CO32- and HCO3- content of the mineral dust. In contrast, the high R-C/A values for submicron aerosols ( < 1.1 gm) were likely caused by the presence of water-soluble organic anions. The Rett, values for all size fractions were lower on hazy days than clean days, indicating that aerosol acidity was enhanced on polluted days. Simiar temporal trend between R-C/A and in-situ pH indicated that R-C/A was a good indicator of aerosol acidity in fine mode aerosol. The SO42- and NO3- contents in fine particles were completely neutralized as the Rcm values for PM2.1 approached unity, and mean values of R-C/A were 1.34 and 1.16 during the transition and polluted periods, respectively. The lowest Rc/A values were observed in the size fraction with the highest concentrations of SO42-, NO3- and NH4+ (SNA) and concentrations of SNA increased with the increasing aerosol acidity. Significant correlations between [NO3-]/[SO42-] and [NH4+ V[SO42-] during NH4+-rich conditions in fine size fractions indicated fine mode NO3- in Beijing was mainly formed by gas-phase homogeneous reaction between the ambient NH3 and HNO3. |
英文关键词 | Ion balance Acidity Size distribution Haze |
领域 | 地球科学 |
收录类别 | SCI-E |
WOS记录号 | WOS:000418981500012 |
WOS关键词 | POLLUTION EPISODES ; INORGANIC-IONS ; ORGANIC-ACIDS ; AEROSOL ; PM2.5 ; SULFATE ; NITRATE ; CITIES ; PH |
WOS类目 | Meteorology & Atmospheric Sciences |
WOS研究方向 | Meteorology & Atmospheric Sciences |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://119.78.100.173/C666/handle/2XK7JSWQ/15190 |
专题 | 地球科学 |
作者单位 | Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Layer Phys & Atm, Bj 100029, Peoples R China |
推荐引用方式 GB/T 7714 | Tian, Shili,Pan, Yuepeng,Wang, Yuesi. Ion balance and acidity of size-segregated particles during haze episodes in urban Beijing[J]. ATMOSPHERIC RESEARCH,2018,201:159-167. |
APA | Tian, Shili,Pan, Yuepeng,&Wang, Yuesi.(2018).Ion balance and acidity of size-segregated particles during haze episodes in urban Beijing.ATMOSPHERIC RESEARCH,201,159-167. |
MLA | Tian, Shili,et al."Ion balance and acidity of size-segregated particles during haze episodes in urban Beijing".ATMOSPHERIC RESEARCH 201(2018):159-167. |
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